Outcrop vs. Boulder
An outcrop is bedrock in place, while a boulder is a transported block. A boulder can be collectible, but it does not reliably tell you what is in the ground at that exact location.
Outcrop vs. Float
Float is loose material that has moved from its source by gravity, water, or erosion. Outcrop shows the original context; float is a clue that helps you find the outcrop.
Outcrop vs. Quarry Face
A quarry face can resemble an outcrop, but it is human-made and may be restricted. Even if material is visible, access and collecting rules can be very different from a natural exposure.